Analyzing the nuances of water quality data?

Water quality monitors and data can confirm if chlorine, or other water quality parameters, are generally at levels required by the water company and regulators of the water industry.

At present this does not replace regulated laboratory sampling for more complex aspects of water quality. Modern and reliable equipment for spot sampling and permanent sampling, through a range of sensors*, at sites is essential for reservoir health checks. You can have confidence very quickly that the data being reviewed is accurate and reliable. This will provide that indicative health check of the reservoirs condition. Also, reservoir operation can be determined from data nuances.

The data set below is a case in point of how chlorine data, reservoir level data and a little bit of local knowledge completely overturned previous understanding of the reservoir operation and highlighted the risks at this site.

The data confirms chlorine arriving at a reservoir is sufficiently high that it should provide a suitably disinfected outlet residual of the reservoir.

What do nuances of this data tell us before we look at the outlet?

For information the reservoir level indicates an inflow filling by rising blue line slope and not filling on down slope (confirmed by meter flow at pumping site supplying this reservoir). Out flow can occur at all times. The inlet main remains pressurised at all times either by inflow or outflow via cross connections at the reservoir site causing a reverse flow toward the supplying pump site. Chlorine dosing occurs at the pump site supplying the reservoir.

At point A the reservoir stops filling and outflow only is shown by downward slope of reservoir level.

Up to and past point A chlorine residual being monitored is stable. Sometime later at point B the residual level starts to drop dramatically. The residual then levels out up to point C.

This indicates that the main and the supply to the analyser for the inlet monitor holds some of the chlorinated water at the level being supplied for a short time. As the pipe feeds in reverse the chlorine starts to dissipate and the analysers starts to record reservoir content water, supplied from the outlet mains cross connected to the inlet main.

At point C the reservoir starts to fill again and a sharp increase in residual is seen. This indicates a retention of chlorinated water in the inlet main and shows there is a flow but not significant in the reverse direction. The forward inlet flow causes the residual to rises quickly. Further evidence for this is due to the second step in residual level at point D as water that chlorine has not dissipated as much, starts to arrive at the reservoir and later the dosing at the pump site takes effect. At point E the dosing effect levels off, showing the residual now being a constant in the supply water. This pattern is repeated on the regular fill and empty cycle of the reservoir.

Adding outlet data to the above brings further understanding of the water quality in this reservoir and the way the site operates due to its mains connectivity.

The two additional lines are both outlet chlorine residuals. The data is from monitors on separate outlets of the reservoir. Prior to point A both outlet residuals are at a steady level. This is at the time when the reservoir is filling. Around point B both outlet monitors show the residual levels start to fall as the reservoir stops filling. Between points B and C, the outlet residuals slowly fall as the reservoir empties until the reservoir starts to fill again at point C. This profile is seen too in the inlet residual trace. Why is this happening? And how does the data help us understand what is occurring?

The flow to the cell is now from water in the main with only background residual and that chlorine content is slowly degrading. Issues are similar to the previous bullet point and again of little concern unless there are low level alarms that will shut the system down. If there is concern around having low alarms too low, then software and controls at the site will need refining. 

Although the data is from a post dose monitor a similar thing can happen on a Pre-Dose analyser, if fitted. In most cases it is of little consequence and understanding why it is happening may be all that is required if no control or warnings are related to a pre-dose analyser. The exception to this would be with a feed forward dosing system. The following conclusions can be reached without any knowledge of the inlet and outlet mains configuration. Confirmation of the mains connectivity and valve positions was later provided when the anomalies here were discussed and were presented to the water company.

Prior to points A and B all the three monitors were recording reasonably high inlet chlorine levels in the supply to the reservoir. This is due to the connectivity at site of the inlet mains and outlet mains. In effect the inlet supply water is by passing the reservoir at filling times.

An unknown percentage of the water being suppled to site is going straight into supply from the inlet to the outlet mains and the rest is filling the reservoir.  It is possible to calculate the percentages, but to date this has not been done. Bypassing is confirmed by what happens after point C when the reservoir starts to fill.

All three monitors show an increase in chlorine residual and after point E start to level off as a steady residual from the dosed supply water is seen at the reservoir site. If the inlet and outlet mains were not open to each other this could not happen and the mirroring of the profiles confirms too the by passing of the reservoir as inlet water and outlet water residual follow the same profiles. Though the residuals are different levels this is due to the sensors possibly requiring calibrations and or the travel time of the water to the sensors. This does not mean there is a flaw in the conclusions as the profiles are the key to these deductions.

Of interest to is the lower chlorine levels between B and C when they appear to slowly taper off. While the reservoir is emptying the residual eventually seem to follow a slow decline in residual levels to point C when the fill starts again. This slow decline and no apparent even or level profile would indicate that the true residual in the reservoir is not seen as the downhill gradient does not bottom out. Though the residual seen between B and C are the closest indicative levels of chlorine in the reservoir. In this data set the true reservoir residual is not visible due to the fill starting and thus re elevating the chlorine levels to the inlet residual after point C, through D and to and beyond E.

Conclusions

  • The reservoir turnover or change of water internally to the reservoir is poor and a potential quality risk.
  • The regulatory samples are not guaranteed to be a true representative of water quality at this reservoir.
  • Customers will see varying chlorine residual levels and not an even steady level.
  • Local company knowledge of this site was worryingly flawed.
  • Lack of knowledge around this site’s operation would hinder evaluation for any customer impacts should an event occur.
  • There is significant risk of “dead” quality areas in the reservoir and slow or static water in pipes at this location containing poor quality water.
  • An event could pull potentially poor-quality water into supply to customers.

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Analyzing the nuances of water quality data?

Intelligent gas detectors play a vital safety role in areas where staff are routinely present, offering protection from harmful levels of toxic gases. 

With high levels of chlorine used as one of the most common forms of disinfection, gas detectors are routinely used to monitor ambient air in order to provide an early warning of the presence of toxic gases.

As harmful gases, such as chlorine, are heavier than air, their presence may not always be immediately obvious to staff entering an enclosed space, posing a serious health and safety risk.

One of our valued customers, who uses chlorine gas for disinfection, recently required an updated and improved detection system to measure for background levels of this harmful gas to ensure efficacy and staff safety. The F12/D toxic gas detector, featuring a built-in traffic light system, was installed to provide real-time data, along with visual and audible alarms to indicate when specific levels of gases have been reached. The alarm system is triggered when the chlorine level hits a high (amber) or high high (red) set point.

ATi F12D Chlorine gas detectors with AutoTest

The sensor was placed within the dosing room and the display and strobe outside to prevent staff from entering until it was safe. By combining this warning system with ATi’s pioneering AutoTest feature, which tests and verifies itself daily with self-generated target gas rather than a surrogate, health and safety managers can be certain that the sensors work and the environment is safe. This allows for reliable monitoring without expensive third party call-outs to test and verify gas sensors.

The unique AutoTest self-check system provides reliable response checks to ensure system integrity for a range of toxic gases, which is ideal for industries such as leisure, food and beverage, industrial, agriculture and aquaculture.

For many workers, the smell of gases have become part and parcel of their working environment, not knowing if the levels being inhaled for hours at a time is a major health concern for both employer and employee. Gases such as chlorine can very quickly become debilitating, critically effecting breathing and vision in a matter of seconds. However, the versatility of ATi’s gas detection range provides gold standard systems that are simple to install, operate and maintain, offering peace of mind.

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Hydrogen Sulfide monitoring for marine applications

The ATi F12D and ATEX approved F12iS (intrinsically safe) Hydrogen Sulfide gas detection monitors, with wet sensor technology, are ideally suited for marine applications with cold, damp, salty and wet conditions. Our customer required a reliable and accurate H2S gas detection system to ensure the safety and protection of staff during the transfer or waste materials. 

The F12D and F12iS monitors have been designed for direct installation into a stack or duct, giving a representative measurement as changes occur from within the stack. The sensors can be simply swapped out and replaced with a pre-calibrated sensor if and when required. This simple operation can be carried out by site personnel and also used to validate a reading if required. 

Odour control monitoring installed directly to wet stack

Pre-calibrated sensors are kept in a charged, polarizing unit, with the user replacing the sensors on a quarterly or half-year rotation. The added membrane allows for continuous monitoring throughout the year and in wet applications. This means that the sensor can be connected to inlets and outlets of OCU’s (odour control units) to test for efficacy of the filtration (media). 

The intrinsically safe F12iS can be used in both wet and ATEX required applications, which means that conditioning the sample is not needed. Conditioning ‘sampling’ systems can be costly and are designed to take out a sample, heat it and then run it past dry sensors. These systems have many moving parts and often require servicing by third party companies.

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Analyzing the nuances of water quality data?

ATi’s IsoMon dual-channel gas detection system is specifically designed for monitoring complete decontamination cycles from start to finish, in isolators or other chambers, using hydrogen peroxide sterilisation (H2O2).

This unique system was primarily developed to address the needs of the medical and pharmaceutical industries, but can also be used within food packaging, biological, defence and industrial settings.

IsoMon is a fist-of-its-kind gas detector that allows both high and low value measurement of hydrogen peroxide levels, providing users with reliable validation data regarding the sterilization of aseptic environments. The instrument is designed to pull samples from an enclosed space, delivering them to two separate measuring cells, one for high concentration and the other for low concentration.

Hydrogen Peroxide Gas

ATi are one of the only gas sensor companies in  the world that manufacture an accurate sensor  that can be used to protect staff. H2O2 is released  into the air during the decontamination process (fogging) and should be monitored as part of your Quality Controls Programs. Rooms, surfaces and equipment can be sterilized multiple times per day with higher levels of H2O2  than ever before, increasing the risk to those working  close to them.

Monitoring H2O2  levels enables you to ensure sterile levels subsequently drop to safe, ambient levels post sterilisation. This continuous monitoring allows you to validate and demonstrate that the vapour in the air is safe, posing no risk to staff and patients. Generating the right amount of gas is vital for efficacy over prolonged periods. It is therefore essential to understand and accurately monitor H2O2 levels with a pre-calibrated monitor.

How does it work?

The IsoMon monitoring system draws the sample through Teflon® lined tubing, using an internal two-channel sample pump, with each pump head providing flow to a separate sensor. A common sample inlet port is provided, but an integral solenoid valve controls sample delivery to the low-concentration sensor.

IsoMon

The solenoid valve is controlled by the high-concentration monitor to avoid saturation of the low-concentration sensor. The solenoid is activated when the measured value on the high concentration sensor reaches 30ppm and will reset at 28ppm. When the solenoid switches, ambient air is drawn into the low-concentration unit to ensure that it is ready to operate when gas or vapour levels fall back to a lower level. This is done to ensure that the low level sensor is not saturated by long exposure at high concentration.

The high-concentration measuring channel can measure to a maximum of 2000ppm. However, it is possible to set the data logging and analogue output range to a smaller, full-scale value. As shipped from the factory, the high-concentration channel will be programmed for a logging range of 0-1000ppm. With this adjustment, the display will indicate values up to 2000ppm, but the internal data logger will not log values above 1000ppm. This is done to improve data-logger resolution when  the instrument is measuring at lower levels.  The low-concentration channel has a maximum measuring value of 200ppm, but is set for a logging range of 0-20ppm as the default.

As with the high-concentration channel, the  low-concentration channel can be programmed for any full-scale logging range within the limits of  the sensor.

ATi H10 smart gas sensor

The sensor used for hydrogen peroxide monitoring is the ATi H10 smart gas sensor with integral memory. The sensor contains calibration data, specific only to the sensor, and can easily be returned to ATi for recalibration. This eliminates the need for users to set up special calibration equipment. Standby sensors with up-to-date calibrations can be quickly inserted into the individual channels when installed.

Data logging of concentrations is done in each measuring channel separately. The accumulated data may be downloaded to a PC using the RS-232 connection. Data is transferred to files for use in Microsoft Excel or other data handling programs. Data intervals of 1 second up to 60 seconds may be selected, with data storage from 11 days to more than 400 days depending on the storage interval. While the IsoMon is a transportable device designed for use in a variety of locations, external power is required to operate the monitor.

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Non-interuptive water quality sampling

ATi recently worked in partnership with Panton McLeod and one of the UK’s largest water utilities, to facilitate a sampling survey, as part of two service reservoir water quality inspections.

Several samples were required from different parts of the reservoir and at various depths. The construction of the reservoirs and lack of access meant any kind of meaningful dip-sampling would not be adequate for providing enough samples and the spread would not be representative of the reservoir content. It was apparent that a submersible ROV (remotely operated vehicle) would be required that could be used or adapted to travel to the different parts and depths of the reservoir.

In order to provide the best service for this bespoke project, ATi worked closely with Panton McLeod, renowned inspection, cleaning and water asset performance specialists who provide innovative products and solutions, particularly for the cleaning and inspection of service reservoirs.

During the planning and preparation for this project, a consultative workshop took place at Panton McLeod’s headquarters in Tweedbank, Galashiels, where a working mock-up was configured to test the Panton McLeod ROV with an attached umbilical cord to ATi’s SiteBox portable water quality monitoring and control unit.

This test unit gave an accurate prototype of what would happen on site, with the successful development and testing giving high levels of confidence that this bespoke, collaborative solution would provide reliable and consistent results onsite.

Workshop trial

After the successful workshop trial, discussions were opened up with the water company, showcasing this new option of internal reservoir water quality testing. Foremost, it was recognised that not all samples being taken would be equivalent to regulatory samples taken and tested in a laboratory.

It was considered that chlorine monitoring was the most essential using the SiteBox and its industry-leading M-Node digital sensors, with turbidity, dissolved oxygen and pH being beneficial for an indicative quality of the reservoir content. These samples would highlight areas of concern within the reservoir. Other samples could be taken for laboratory testing via the umbilical pipe feeding the SiteBox.

SiteBox water quality control unit

Planning for the onsite sampling included consultation with all parties for risk assessment and RAMS (Risk Assessment Method Statement) preparation. Hygiene was of priority concern as the reservoirs were in use with potable water. No contamination would be allowed and all parties had to provide RAMS to confirm no risks were being taken. Even the risk of open hatches had to be mitigated, even for rain (see picture with tent over hatch). RAMS were to include all aspects of undertaking the task for all parties i.e. ATi and Panton McLeod both presented to the water company, who also had to comply with their own operational rules and standards.

A methodology was developed by the water company’s technical team and with consultation with the Reservoir Operational Section. ATi and Panton McLeod were also involved to confirm the methodology proposal would work. A map of the reservoir was split into grid-like sections and the number of points for sampling were determined by location and also at what depth. Each location would have a sample at the bottom, middle and near top of the level of water in the reservoir. The depth of this reservoir and water contained at the time of the testing determined that three samples should be taken at the chosen depths. Shallower reservoirs or emptier reservoirs may only require one or two depth related samples.

Panton McLeod operators set up the ROV and also the site, so safe access to the water space could be achieved. All equipment was sanitised for access to potable water. Preparation of site and deployment of ROV with ATi’s SiteBox portable water quality monitor.

Continuous monitoring for hygiene purposes was maintained for the duration of the exercises, as more than one site and two visits to each site on different days was accomplished. At each occasion the ROV was deployed into the reservoir and moved to the pre-determined sample points. Once at a sample point, the ROV remained stationary for 10 to 15 minutes to allow for the water from that point to travel down the length of the umbilical tube to the SiteBox.

At the ATi SiteBox, the position, time and the readings were noted. Regular chlorine checks by manual testing were also taken to confirm sensor accuracy. Some ‘bottle’ samples were also taken for laboratory testing. The lab results were not shared with ATi or Panton McLeod, however no detrimental results were found. Chlorine levels within the reservoirs identified various chlorine strengths across the reservoir’s areas and depths. All were within acceptable levels. Areas of reduced chlorines were identified but, in these instances, did not generate any actions but did identify areas of concern. They also indicated some differences, though not detrimental, of water quality in different areas and depths of the reservoirs

Conclusion

This new concept of implementing condition checks of a reservoirs content to completion of sampling, utilising a bespoke water quality monitoring approach was a resounding success. The research and trials conducted indicated that ATi’s SiteBox was the most suitable solution, in collaboration with Panton McLeod’s specialist ROV, due it it’s modular monitoring, control and policing nature. With the ability to monitor live readings, SiteBox provided the customer with clear and consistent data throughout the operation, along with taking samples, demonstrating that the reservoirs met company and regulatory standards. The data would assist in assessing future issues and enable predictive maintenance for specific needs identified.

This innovative ‘Lift & Shift’ method of water quality monitoring was vital in identifying and assessing issues within the service reservoirs, along with asset performance. Being proactive at this early stage can prevent shutting down reservoirs, saving on unnecessary and costly project work in the future. The water company were pleased with the results, the interpretation of the data recorded and what it told them about their reservoirs. Future use of the equipment and collaboration between ATi and Panton McLeod with other water companies will certainly provide an accurate and beneficial insight into the condition of any potable water reservoir surveyed.

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Analyzing the nuances of water quality data?

The Punta Gorda WTP is a 10MGD surface drinking water facility located just east of Punta Gorda Florida. The process includes floc tanks, four Solids Contact Units (SCUs) which are a form of upflow clarifier, which then feed two Greenleaf Filters with four cells each. The filters are backwashed every 70 hours regardless of head loss. High backwash flow rate is 5200gpm. The total cost to treat 1000 gallons of drinking water is $1.73 (£1.37).

The plant became aware of the FilterSmart Media Level and Turbidity Monitors in 2013 when the Utilities Director attended a presentation on FilterSmart at the AL/FL Joint Rural Water Conference and information was passed to the Plant Supervisor. A field trial was arranged and equipment purchased to outfit the filters.

Filter run times extended from 70 to 120 hours

During the field trial, it was noted that the loading in the filters was very light (see figure 1). This can be seen in the relatively low turbidity measured during the backwash. Since the backwash schedule was based on time and not head loss, the suggestion was made to incrementally increase the Filter Run Times (FRTs) until the head loss value was reached. FRTs were increased to roughly 150 hours at one point, but were backed off to 120 hours due to various concerns. This initial process adjustment resulted in a 42% decrease in backwash water consumption annually at a value of approximately $65,000 (£50,400).

Figure 1. Graph of Media Level and Turbidity vs Time. Max Turbidity is 50NTU. Media expansion is approx 30%.

High rate backwash flow duration reduced four minutes

Once the instruments were purchased and installed, backwash data also indicated that the high rate portion of the backwash was longer than necessary, and was reduced by four minutes (see figure 2). This adjustment resulted in a savings of approximately 22,100 gallons of wash water per wash, at a value of $21,000 (£16,000) annually.

Together, these two simple adjustments to the backwash process resulted in $86,000 (£66,700) in savings the first year. These savings are more than twice the total price of the instruments.

Figure 2. Four minutes of over-washing eliminated.

Dramatic savings through sludge measurement in drying & handling process

The flow of water in the SCUs is up through a blanket of sludge and into collection pipes which send the water to the filters. The sludge blanket rises to a level where it cascades into a trough, from which it is pumped to the drying process (see figure 3).

Figure 3. Solids Contact Unit.

An EchoSmart sludge blanket monitor was installed in each of the four sludge troughs, with the signals used to control the sludge pumps. The goal was to keep the sludge level in the troughs within a 6-8 inch range. Previously, the sludge pumps were turned on and off manually, which produced inconsistent results. Using the EchoSmart blanket level to control the pumps eliminated these inconsistencies, and greatly reduced the hydraulic loading to the sludge drying train (see figure 4).

Figure 4. Blanket Level Trend in SCU.

Perhaps the most unexpected and significant savings came from the sludge drying process. Backwash water and the sludge from the SCUs first go to a decant tank where the sludge settles and the supernatant is returned to the headworks. The settled sludge goes to one of a dozen three-walled drying cells with underdrains. A layer of sand is spread in the cells to protect the underdrain from the action of the front-end loader. Previously, all 12 cells were needed. With the reduced hydraulic loading, only one or two cells are now needed. Consequently, the amount of sand has been greatly reduced. According to the Plant Supervisor:

“We used to order between $200,000 (£155,200) and $300,000 (£232,800) of sand a year. Since we implemented the blanket monitors, we haven’t ordered sand in a couple of years.” 

Brian Fuller, Utilities Director

In addition to these documented savings, there are others that haven’t been documented. For example, the driver of the front end loader is free to resume other maintenance activities. Fuel for the front end loader is reduced. Polymer use prior to the sludge press has been reduced. Tipping fees to haul the sludge to the dump have been greatly reduced.

Summary

All told, the savings to the plant in the first couple of years after installing the FilterSmart and EchoSmart monitors could easily reach over $500,000 (£419,000).

“We love these instruments. They’ve given us data that we can use to make decisions that have saved us a lot of money!”

Brian Fuller, Utilities Director

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  • Environment
  • Sensors
  • Septicity
  • Sewer
  • Sludge Blanket
  • Wastewater
  • Water Quality

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A global company with a caring culture. We have a team of experts on hand to help with any product or support query you may have. Contact us and experience ATi’s exemplary customer support.

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